What Is Foam?
Foams are materials formed by trapping pockets of gas in a liquid or solid. A bath sponge and the head on a glass of beer are examples of foams. In most foams, the volume of gas is large, with thin films of liquid or solid separating the regions of gas.
Background
Foam rubber is found in a wide range of applications, from cushioning in automobile seats and furniture to insulation in walls and appliances to soles and heels in footwear. Foams are made by forming gas bubbles in a plastic mixture, with the use of a blowing agent. Foam manufacture is either a continuous process for making laminate or slabstock or a batch process for making various shapes by cutting or molding.
There are two basic types of foam. Flexible foams have an open cell structure and can be produced in both high and low densities. Applications include cushioning for furniture and automobiles, mattresses and pillows, automotive trim, and shoe soling. Rigid foams are highly cross-linked polymers with a closed cell structure that prevents gas movement. Their main application is as insulation for buildings, refrigerators and freezers and refrigerated transport vehicles.
The molecular structure, amount, and reaction temperature of each ingredient determine the characteristics and subsequent use of the foam. Therefore, each formulation must be designed with the proper ingredients to achieve the desired properties of the final material. For instance, a switch in blowing agent may require an increase in this additive to maintain thermal properties. Increasing the amount of blowing agent requires more water and a switch in surfactants to maintain optimum bubble sizes and formation rates during foaming. The density of the foam is determined by the amount of blowing. The stiffness and hardness of polyurethane can also be tailored by changing the level of flexible polyol in the chemical formulation. By mixing different combinations of the starting materials, the rates of the reactions and overall rate of cure during processing can be controlled.
Raw Materials
Most foams consist of the following chemicals: 50% polyol, 40% polyisocyanates, and 10% water and other chemicals. Polyisocyanates and polyols are liquid polymers that, when combined with water, produce an exothermic (heat generating) reaction forming the polyurethane. The two polyisocyanates most commonly used are diphenylethane diisocyanate (MDI) and toluene diisocyanate (TDI). Both are derived from readily available petrochemicals and are manufactured by well-established chemical processes. Though MDI is chemically more complex than TDI, this complexity allows its composition to be tailored for each specific application. MDI is generally used in rigid foams, whereas TDI is typically used for flexible foam applications. Blends of MDI and TDI are also used.
Polyols are active hydrogen monomers based on polyesters, polyethers, or hydrocarbon materials that contain at least two active hydrogen atoms. The type of polyol used will determine whether the foam produced is flexible or rigid. Since most polyols immediately react with isocyanates when added together, it is easy to combine the polymerization and shaping processes into one step. During the polymerization proccess, the polyol and polyisocyanate molecules link and interconnect together to form a three dimensional material.
A wide range of additives are also used. Catalysts (tin and amines) speed up the reaction, allowing large volume production runs. Blowing agents that form gas bubbles in the polymerizing mixture, are required to produce foam. The amount of blowing can be tailored by adjusting the level of water. Flexible foams are typically made using the carbon dioxide formed during the reaction of water with isocyanate. Rigid foams use hydrochlorofluorocarbons (HCFCs), hydrofluorocarbons (HfCs), and pentanes as the blowing agents.
Surfactants are used for controlling the size of bubbles and include silicones, polyethers, and similar materials. Other additives that may be used include cross-linking agents, chain-extending agents, fillers, flame retardants and coloring materials, depending on the
The Manufacturing
Process
Polymerization rates for most industrial polyurethanes range from several seconds to about five minutes. Slower reacting formulations can be mixed and molded by hand, but require long cycle times. Faster systems provide shorter cycle times but must use machines for mixing. Polyurethane formulations are generally processed into a wide range of products by reactive molding, spraying, or open-pouring techniques.
Material Preparation
- 1 The liquid chemicals are delivered either by railroad tanker cars or tank trucks and pumped into large holding tanks. From there, the chemicals are pumped into smaller heated mixing tanks, and are kept separate if they react with each other. For continuous manufacture of foam such as slabstock, more than two monomer streams are typically used.
Dispensing And Mixing
- 2 Continuous dispensing (also called open pouring or free-rise) is used in the production of rigid and flexible low-density foams. A specific amount of each chemical, measured by metered pumps, is fed from the mixing tanks into a mixing head, where the blending of the chemicals take place. The reactive components are poured onto a moving surface or conveyor belt, where the foam rises and cures to form slabstock.
Cutting And Curing
- 3 As the foam moves toward the end of the conveyor belt, it is automatically cut by a horizontal bandsaw into smaller pieces, usually 12 ft (3.66 m) long sections. After cutting, the foam sections are cured at room temperature for 12 hours or more. They are not stacked since they are not firm enough to withstand any weight. After curing, a second automatic bandsaw cuts the sections into the desired thickness. Other shapes can also be cut.
Other Forming Processes
- 4 A continuous lamination process is used to form rigid foam laminate insulation panels known as boardstock. For appliance insulation, liquid chemicals are injected between Chemicals are dispensed in a continuous fashion called open pouring or free-rise. Once blended, the reactive components are poured onto a conveyor belt, where the foam rises and cures to form slabstock. Next, the slabstock is conveyored through a series of automatic bandsaws that cut the slabstock to premeasured widths and thicknesses.the inner and outer walls of the appliance cabinet, where they undergo the foaming process.
- 5 For flexible foam molding, dispensing machines are used to vary the output of chemicals or the component ratios during the pour. This allows the production of molded foams with dual hardness. Molded foam articles with solid surface skin are made from liquid chemicals in a single step, using carbon dioxide as the sole blowing agent. Automotive cushions are made by molding flexible foam behind a pre-shaped fabric cover. This process reduces the number of steps in the manufacture of car seats.
Foam Prices In Ghana:
Single Size (36”x 75”) GHc 910.00
Medium Size (42”x75”) Ghc 1,070.00
Large Size (54”x75”) Ghc 1,350.00
Queen Size (72”x75”) Ghc 1,800.00
King Size (84”x74”) Ghc 2,090.00